赣南三地绿茶中微量元素含量的测定

选用了赣南宁都小布岩茶、上犹梅林毛尖茶及定南六台山茶，用火焰原子吸收分光光度法对这三类绿茶中的微量元素Ca、Zn、Mg、Mn、Fe、Cu、Pb的含量进行了测定。方法简单，精密度和灵敏度高，回收率为101％-92％，结果可靠。     

方阱链流体在固液界面分布的密度泛函理论研究

应用Yethiraj的加权密度近似泛函理论研究平板狭缝中方阱链流体的密度分布，系统的Helm holtz自由能泛函分为理想气体的贡献利剩余贡献两部分，其中剩余贡献部分分别采用刘洪 来等人建立的基于空穴相关函数的方阱链流体状态方程和Gil-Villegas等人提出的统计缔合 流体理论状态方程(SAFT-VR)结合简单加权密度近似计算.考察了不同链长、温度、系统密度 和壁面吸引强度下平板狭缝中方阱链流体的密度分布，并与Monte Carlo(MC)模拟结果进行 了比较.结果表明采用不同的状态方程对密度分布的计算有明显的影响，对于受限于硬壁狭 缝中的方阱链流体，温度和密度比较高时，两种状态方程计算的结果均与MC模拟符合得比较 好，在低温和低密度下效果变差，SAFT-VR方程的计算结果更接近于MC模拟结果.对于受限于 方阱壁狭缝中的方阱链流体，由于系统密度分布的非均匀性加强，采用两种状态方程计算的 结果均与MC模拟结果有一定偏差，寻找更合适的权重函数是进一步改进的关键. 关键词： 密度泛函理论 非均匀流体 密度分布 固液界面 方阱链     

火场残留无痕迹燃烧物的物证分析(Ⅰ)

基于硫酸介质中重铬酸钾氧化乙醇的反应,建立了火场残留无痕迹助燃剂乙醇的定性和定量分析方法。定性分析检出限量5μg,最低检出浓度0.20mg.L-1。定量分析的检出限1.22mg.L-1,线性范围为0.10~3.2000g.L-1。将方法用于火灾现场残留的乙醇分析,结果满意。     

A proof of Selberg's orthogonality for automorphic L-functions

Let π and π′ be automorphic irreducible cuspidal representations of GL_m(Q_A) and GL_m′(Q_A), respectively. Assume that π and π′ are unitary and at least one of them is self-contragredient. In this article we will give an unconditional proof of an orthogonality for π and π′, weighted by the von Mangoldt function Λ(n) and 1−n/x. We then remove the weighting factor 1−n/x and prove the Selberg orthogonality conjecture for automorphic L-functions L(s,π) and L(s,π′), unconditionally for m≤4 and m′≤4, and under the Hypothesis H of Rudnick and Sarnak [20] in other cases. This proof of Selberg's orthogonality removes such an assumption in the computation of superposition distribution of normalized nontrivial zeros of distinct automorphic L-functions by Liu and Ye [12].     

空间应用的低温工质

介绍了低温流体在低温低压近临界区以及稀薄状态下的特殊性质,并详细介绍了几种低温工质的特点以及它们在空间技术中的应用。     

On Basic Constraint Qualifications for Infinite System of Convex Inequalities in Banach Spaces

The BCQ and the Abadie CQ for infinite systems of convex inequalities in Banach spaces are characterized in terms of the upper semi-continuity of the convex cones generated by the subdifferentials of active convex functions. Some relationships with other constraint qualifications such as the CPLV and the Slate condition are also studied. Applications in best approximation theory are provided.     

Preparation and characterization of novel hyperbranched poly(amido amine)s from Michael addition polymerizations of trifunctional amines with diacrylamides

Novel hyperbranched poly(amido amine)s containing tertiary amines in the backbones and acryl as terminal groups were synthesized via the Michael addition polymerizations of trifunctional amines with twofold molar diacrylamide. The hyperbranched structures of these poly(amido amine)s were verified by ¹³C NMR (INVGATE). The polymerization mechanisms were clarified by following the polymerization process with NMR method, and the results show that the reactivity of secondary amine formed in situ is much lower than that of the secondary amine in 1‐(2‐aminoethyl) piperazine (AEPZ) ring and the primary amine. The secondary amine formed in situ was almost kept out of the reaction before the primary and secondary amines in AEPZ were consumed, leading to the formation of the AB2 intermediate, and the further reaction of the AB2 yielded the hyperbranched polymers. The molecular weights and properties of poly(amindo amine)s obtained were characterized by GPC, DSC, and TGA, respectively. Based on the reaction of active acryl groups in the polymers obtained with glucosamine, hyperbranched polymers containing sugar were formed. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 5127–5137, 2005     

强流脉冲离子束辐照靶材烧蚀效应二维数值研究

对强流脉冲离子束(IPIB)辐照Ti靶的烧蚀效应进行了二维数值研究.得到了表面烧蚀物质随脉冲时间的变化关系.得出TEMP Ⅱ 型加速器产生的脉冲束流辐照靶材时引起的汽、液化均是从表面开始、并且汽化过程中表面物质被层层烧蚀的结论.同时，得到中心区的平均烧蚀速度为10m/s 数量级，它远小于产生的烧蚀等离子体的喷发速度.得到脉冲期间靶材内部不同位置烧蚀斑痕形状的时间演化过程，以及束流中含有的离子种类分额不同时IPIB辐照过程产生的不同效果. 关键词： 强流脉冲离子束 靶 烧蚀过程 二维数值模拟